Electroreduction of Benzalacetone in N,N -dimethylformamideReport as inadecuate

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Croatica Chemica Acta, Vol.61 No.4 December 1988. -

The electrochemical reduction of benzalacetone BA has been

studied at mercury cathodes in N,N-dimethylformamide solutions

by the techniques of cyclic voltammetry and controlled potential

coulometry. The radical anion BA- forms ion pairs with tetraethylammonium cations and then disappears in oligomerization

processes. Atentative structureof the dimer BA- BA-


C2H54N+is suggested on the basis of quantum mechanical callations.

Author: Slawomir Filipek - ; Department of Chemistry, University of Warsaw, 1 Pasteur Str., 02-093 Warszawa Poland Elžbieta Wagner - ; D

Source: http://hrcak.srce.hr/


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