DIRECT OBSERVATION OF THE TRANSITION STATE OF A PHOTOCHEMICAL REACTION ; THE Hg3 P1, Cl2 SYSTEMReport as inadecuate




DIRECT OBSERVATION OF THE TRANSITION STATE OF A PHOTOCHEMICAL REACTION ; THE Hg3 P1, Cl2 SYSTEM - Download this document for free, or read online. Document in PDF available to download.



Abstract : A novel method designed to observe the collision complex of a photochemical reaction is reported here. The reactants Hg, Cl2 are frozen in a van der Waals complex Hg-Cl2, and then promoted by an optical excitation 250 nm to the reactive state. The broad complex action spectrum, presumably due to the Hg+-Cl-2 intermediate, is monitored through the HgCl B2Σ+ fluorescence.





Author: C. Jouvet B. Soep

Source: https://hal.archives-ouvertes.fr/



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