The Influence of f Orbitals on δ Metal BondsReport as inadecuate

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Croatica Chemica Acta, Vol.64 No.3 December 1991. -

Some 3 metal bonds have been studied by using the recently proposed population analysis based on hybrid orbitals. The results show that the 6 metal bonds are formed by overlap of the d-f hybrid orbitals of the metal atoms and that the f orbitals play an important role in the 6 bonds. Under the influence of the f orbitals on the 6 bonds, the densities of the 3 electrons between the metal atoms increase and their mean kinetic energies decrease. These are of importance to the stability in the S bonds.

Author: Li Ming - ; Department of Chemistry, Southwest China Teachers University, Chongqing, People’s Republic of China Shan Zion - ; D



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