Novel 1,4-Disubstituted Adamantane Stereoisomers: Synthesis and Spectroscopic CharacterizationReport as inadecuate

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Croatica Chemica Acta, Vol.77 No.4 November 2004. -

A series of new 1,4-disubstituted adamantane derivatives e.g., 1-chloro-4-carbethoxymethylene adamantane 3, 1-chloro-4-carbethoxymethyladamantane 4, 1-chloro-4-2-hydroxyethyl adamantane 5, 1-chloro-4-2-bromoethyladamantane 6, 1-bromo-4-2-bromoethyl- adamantane 7, 1-hydroxy-4-carbethoxymethyleneadamantane 8, 1-hydroxy-4-carbethoxymethyl adamantane 9, 1-acetoxy-4-carbethoxymethyladamantane 10, 1-hydroxy-4-2-hydroxyethyl adamantane 11, 1-hydroxy-4-cyanoadamantane 12, 1-hydroxy-4-carboxyadamantane 13, and 1-hydroxy-4-carbmethoxyadamantane 14 have been synthesized, and their respective syn- and anti-isomers have been separated and identified.

adamantane; 1,4-disubstituted adamantane derivative; syn-anti-isomers

Author: Dunja Šafar Cvitaš - ; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, P. O. Box 180, 10002 Zagr



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