Detecting Electron Transport of Amino Acids by Using Conductance MeasurementReport as inadecuate


Detecting Electron Transport of Amino Acids by Using Conductance Measurement


Detecting Electron Transport of Amino Acids by Using Conductance Measurement - Download this document for free, or read online. Document in PDF available to download.

1

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China

2

Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai 200090, China

3

State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, China





*

Author to whom correspondence should be addressed.



Academic Editor: Masateru Taniguchi

Abstract The single molecular conductance of amino acids was measured by a scanning tunneling microscope STM break junction. Conductance measurement of alanine gives out two conductance values at 10−1.85 G0 1095 nS and 10−3.7 G0 15.5 nS, while similar conductance values are also observed for aspartic acid and glutamic acid, which have one more carboxylic acid group compared with alanine. This may show that the backbone of NH2–C–COOH is the primary means of electron transport in the molecular junction of aspartic acid and glutamic acid. However, NH2–C–COOH is not the primary means of electron transport in the methionine junction, which may be caused by the strong interaction of the Au–SMe methyl sulfide bond for the methionine junction. The current work reveals the important role of the anchoring group in the electron transport in different amino acids junctions. View Full-Text

Keywords: amino acid; single-molecule junction; STM break junction; carboxylic acid; amine amino acid; single-molecule junction; STM break junction; carboxylic acid; amine





Author: Wei-Qiong Li 1, Bing Huang 1, Miao-Ling Huang 1, Lin-Lu Peng 1, Ze-Wen Hong 1, Ju-Fang Zheng 1, Wen-Bo Chen 2, Jian-Feng Li 3 and Xiao-Shun Zhou 1,*

Source: http://mdpi.com/



DOWNLOAD PDF




Related documents