Cohalogenation of Allyl and Vinylsilanes using Polymer-bound HaloateI-ReagentsReport as inadecuate




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1

Institut für Organische Chemie der Technischen Universität Clausthal, Leibnizstraße 6, D-38678 Clausthal-Zellerfeld, Germany

2

Institut für Organische Chemie, Universität Hannover, Schneiderberg 1B, D-30167 Hannover, Germany





*

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Abstract Polymer-supported electrophilic halogenateI complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 OH− -form vinyl silanes are converted into epoxysilanes. View Full-Text

Keywords: Cohalogenation; allylsilane; vinylsilane; polymer-supported reagent Cohalogenation; allylsilane; vinylsilane; polymer-supported reagent





Author: Silvie Domann 1, Georgia Sourkouni-Argirusi 1, Nuria Merayo 2, Andreas Schönberger 1 and Andreas Kirschning 2,*

Source: http://mdpi.com/



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