Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and ElectrolysisReport as inadecuate




Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis - Download this document for free, or read online. Document in PDF available to download.

Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan





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Abstract One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.

Keywords: samarium diiodide; electrolysis; cyclization; hydrindanone samarium diiodide; electrolysis; cyclization; hydrindanone





Author: Masakazu Sono * , Natsuko Ise, Tsutomu Shoji and Motoo Tori *

Source: http://mdpi.com/



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