Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFsReport as inadecuate




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1

Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco UPV-EHU, Apdo. 644, 48080 Bilbao, Spain

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Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco UPV-EHU, Apdo. 644, 48080 Bilbao, Spain

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BCMaterials, Parque Tecnológico de Zamudio, Ibaizabal Bidea, Edificio 500-Planta 1, 48160 Derio, Spain





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Academic Editor: Dong-Sheng Li

Abstract Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks SCFs. In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins phenyl, carboxyphenyl and sulfonatophenyl have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities. View Full-Text

Keywords: metalloporphyrin; Solid Coordination Frameworks SCFs; crystal structure; dimensionality metalloporphyrin; Solid Coordination Frameworks SCFs; crystal structure; dimensionality





Author: Arkaitz Fidalgo-Marijuan 1, Eder Amayuelas 1, Gotzone Barandika 2,* , Begoña Bazán 1,3, Miren Karmele Urtiaga 1 and María Isabel Arriortua 1,3

Source: http://mdpi.com/



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