Palladium-Catalyzed Allylation-Benzylation of H-Phosphinate Esters with AlcoholsReport as inadecuate


Palladium-Catalyzed Allylation-Benzylation of H-Phosphinate Esters with Alcohols


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Department of Chemistry and Biochemistry, TCU Box 298860, Texas Christian University, Fort Worth, TX 76129, USA





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Academic Editor: György Keglevich

Abstract The Pd-catalyzed direct alkylation of H-phosphinic acids and hypophosphorous acid with allylic-benzylic alcohols has been described previously. Here, the extension of this methodology to H-phosphinate esters is presented. The new reaction appears general, although its scope is narrower than with the acids, and its mechanism is likely different. Various alcohols are examined in their reaction with phosphinylidene compounds R1R2POH. View Full-Text

Keywords: palladium; cross-coupling; alcohols; H-phosphinate esters; allylation; benzylation palladium; cross-coupling; alcohols; H-phosphinate esters; allylation; benzylation





Author: Anthony Fers-Lidou, Olivier Berger and Jean-Luc Montchamp *

Source: http://mdpi.com/



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