2-5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl-6-4-nitrophen­yl-4-phenyl-1,3-diazabicyclo3.1.0hex-3-eneReport as inadecuate


2-5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl-6-4-nitrophen­yl-4-phenyl-1,3-diazabicyclo3.1.0hex-3-ene


2-5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl-6-4-nitrophen­yl-4-phenyl-1,3-diazabicyclo3.1.0hex-3-ene - Download this document for free, or read online. Document in PDF available to download.

1

Chemistry Group, Faculty of Science, Islamic Azad University, Damghan Branch, 3671639998, Damghan, Iran

2

School of Chemistry, Damghan University, Damghan, 36715-364, Iran





*

Authors to whom correspondence should be addressed.



Abstract As a consequence of one-pot, three-component reaction of trans-2-benzoyl-3-4-nitrophenylaziridine with 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-carbaldehyde and ammonium acetate, 2-5-chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl-6-4-nitrophenyl-4-phenyl-1,3-diazabicyclo3.1.0hex-3-ene was achieved in good yield. The desired photochromic compound display interesting photochromic behavior in the crystalline and solution phase. The structure of the newly synthesized photochromic compound was characterized by elemental analysis, 1H-NMR, 13C-NMR and UV-Visible spectral data. View Full-Text

Keywords: pyrazole; photochromism; bicyclic aziridine; Vilsmeier-Haack reaction pyrazole; photochromism; bicyclic aziridine; Vilsmeier-Haack reaction





Author: Fereshteh Albooye 1,* and Hamzeh Kiyani 2,*

Source: http://mdpi.com/



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