Heterogeneous Catalysis of Polyoxometalate Based Organic–Inorganic HybridsReport as inadecuate




Heterogeneous Catalysis of Polyoxometalate Based Organic–Inorganic Hybrids - Download this document for free, or read online. Document in PDF available to download.

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China





*

Authors to whom correspondence should be addressed.



Academic Editor: Klara Hernadi

Abstract Organic–inorganic hybrid polyoxometalate POM compounds are a subset of materials with unique structures and physical-chemical properties. The combination of metal-organic coordination complexes with classical POMs not only provides a powerful way to gain multifarious new compounds but also affords a new method to modify and functionalize POMs. In parallel with the many reports on the synthesis and structure of new hybrid POM compounds, the application of these compounds for heterogeneous catalysis has also attracted considerable attention. The hybrid POM compounds show noteworthy catalytic performance in acid, oxidation, and even in asymmetric catalytic reactions. This review summarizes the design and synthesis of organic–inorganic hybrid POM compounds and particularly highlights their recent progress in heterogeneous catalysis. View Full-Text

Keywords: polyoxometalates; organic–inorganic hybrid; single crystal; heterogeneous; catalysis polyoxometalates; organic–inorganic hybrid; single crystal; heterogeneous; catalysis





Author: Yuanhang Ren, Meiyin Wang, Xueying Chen, Bin Yue * and Heyong He *

Source: http://mdpi.com/



DOWNLOAD PDF




Related documents