Vol 10: Zirconoarylation of alkynes through p-chloranil-promoted reductive elimination of arylzirconates.Report as inadecuate



 Vol 10: Zirconoarylation of alkynes through p-chloranil-promoted reductive elimination of arylzirconates.


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This article is from Beilstein Journal of Organic Chemistry, volume 10.AbstractA novel method for the zirconoarylation of alkynes was developed. TCQ-promoted reductive elimination of arylzirconate LiCp2ZrArRC≡CR, which was prepared by the reaction of zirconocene–alkyne complexes with aryllithium compounds, afforded trisubstituted alkenylzirconocenes. This reaction can afford multi-substituted olefins with high stereoselectivity.



Author: Yan, Xiaoyu; Chen, Chao; Xi, Chanjuan

Source: https://archive.org/







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