The fate of mercury species in a sub-arctic snowpack during snowmeltReport as inadecuate




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1 LGGE - Laboratoire de glaciologie et géophysique de l-environnement 2 Environment and Climate Change Canada 3 Micro and Trace Analysis Center - Micro and Trace Analysis Center

Abstract : An extensive mercury study was conducted in April 2002 prior to and during the annual melting of a snowpack in a sub-arctic site along the Hudson Bay Canada. Gas-phase measurements show that the snowmelt coincides with an elemental mercury Hg° pulse in the snowpack air far above ambient levels. Additional measurements of inorganic mercury Hg2+ and methylmercury MeHg+ in snow pits, in surface snow and in a meltwater sample clearly reveal that most of Hg is removed from the snow during the first days of snowmelt. We estimate that gas-phase exchanges contribute poorly to remove Hg from the snowpack; consequently during a snowmelt day more than 90% of Hg present in the snow surface is likely released with the meltwater. In arctic areas, where Hg accumulates at an accelerated rate in the snow surfaces Lu et al., 2001 during mercury depletion events MDE, the discharge of this toxic and bio-accumulating pollutant in water systems could be a threat to ecosystems and local indigenous populations.

Keywords : gas exchange methylmercury contamination Canada snowmelt snow mercury





Author: Aurélien Dommergue - Christophe Ferrari - Pierre-Alexis Gauchard - Claude Boutron - Laurier Poissant - Martin Pilote - Petru Jit

Source: https://hal.archives-ouvertes.fr/



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