High Tap Density Spherical Cathode Material Synthesized via Continuous Hydroxide Coprecipitation Method for Advanced Lithium-Ion BatteriesReport as inadecuate




High Tap Density Spherical Cathode Material Synthesized via Continuous Hydroxide Coprecipitation Method for Advanced Lithium-Ion Batteries - Download this document for free, or read online. Document in PDF available to download.

International Journal of ElectrochemistryVolume 2012 2012, Article ID 323560, 9 pages

Research ArticleKey Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, School of Chemistry, Xiangtan University, Hunan, Xiangtan 411105, China

Received 30 September 2011; Accepted 14 December 2011

Academic Editor: Valentin Mirceski

Copyright © 2012 Shunyi Yang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Spherical precursor with narrow size distribution and high tap density has been successfully synthesized by a continuous hydroxide coprecipitation, and is then prepared by mixing the precursor with 6% excess followed by calcinations. The tap density of the obtained powder is as high as 2.61 g  . The powders are characterized by X-ray diffraction XRD, X-ray photoelectron spectroscopy XPS, scanning electron microscope SEM, particle size distribution PSD, and charge-discharge cycling. The XRD studies show that the prepared has a well-ordered layered structure without any impurity phases. Good packing properties of spherical secondary particles about 12 μm consisted of a large number of tiny-thin plate-shape primary particles less than 1 μm, which can be identified from the SEM observations. In the voltage range of 3.0–4.3 V and 2.5–4.6 V, delivers the initial discharge capacity of approximately 175 and 214 mAh g

at a current density of 32 mA g

, and the capacity retention after 50 cycles reaches 98.8% and 90.2%, respectively. Besides, it displays good high-temperature characteristics and excellent rate capability.





Author: Shunyi Yang, Xianyou Wang, Xiukang Yang, Ziling Liu, Qiliang Wei, and Hongbo Shu

Source: https://www.hindawi.com/



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