Experimental Confirmation of the Low-Temperature Oxidation Scheme of AlkanesReport as inadecuate




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1 LRGP - Laboratoire Réactions et Génie des Procédés 2 National Synchrotron Radiation Laboratory

Abstract : Intermediate detected: The design of internal combustion engines relies on a good understanding of the mechanism of the auto-ignition of hydrocarbons.
A key assumption of this mechanism, which was commonly accepted but never proven, has now been experimentally demonstrated: the formation of ketohydroperoxides has been observed under conditions close to those actually observed before the auto-ignition.


Keywords : mass spectrometry photoionization oxidation molecular beams hydroperoxides





Author: Frédérique Battin-Leclerc - Olivier Herbinet - Pierre Alexandre Glaude - René Fournet - Zhongyue Zhou - Liulin Deng - Huijun G

Source: https://hal.archives-ouvertes.fr/



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