Synthesis and chemical reactivity of new zinc porphyrin diazoacetates catalyzed by ruthenium and iron porphyrinsReport as inadecuate




Synthesis and chemical reactivity of new zinc porphyrin diazoacetates catalyzed by ruthenium and iron porphyrins - Download this document for free, or read online. Document in PDF available to download.

1 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : Zinc porphyrin diazoacetates were synthesized from the corresponding bromoacetates by treatment with N,N’-ditosylhydrazine in ∼70% yield. The transfer of carbenoids derived from the porphyrin diazo compounds catalyzed by metalloporphyrins Ru,Fe undergoes dimerization, cyclopropanation, N-H and S-H insertion reactions, respectively

Keywords : Ruthenium porphyrin Meso-phenyl-diazo-porphyrin ester Catalytic carbene transfer iron porphyrin





Author: Daniel Carrié - Hassan Srour - Paul Le Maux - Gérard Simonneaux -

Source: https://hal.archives-ouvertes.fr/



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