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Abstract: Experimental and theoretical results on chemical functionalization ofgraphene are reviewed. Using hydrogenated graphene as a model system, generalprinciples of the chemical functionalization are formulated and discussed. Itis shown that, as a rule, 100% coverage of graphene by complex functionalgroups in contrast with hydrogen and fluorine is unreachable. A possibledestruction of graphene nanoribbons by fluorine is considered. Thefunctionalization of infinite graphene and graphene nanoribbons by oxygen andby hydrofluoric acid is simulated step by step.



Author: D. W. Boukhvalov, M. I. Katsnelson

Source: https://arxiv.org/



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