Deprotonative Cadmation of Functionalized AromaticsReport as inadecuate

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1 CPM - Chimie et Photonique Moléculaires 2 RIKEN - The Institute of Physical and Chemical Research 3 BSI - RIKEN Brain Science Institute 4 Laboratoire de Synthèse Organique Appliquée 5 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : This communication describes the deproto-metalation of a large range of aromatics including heterocycles using a newly developed lithium-cadmium base. The reaction proceeds at room temperature with an excellent chemoselectivity and efficiency, and proved to be regioselective in most cases.

Author: J.M. L-Helgoual-Ch - Ghenia Bentabed-Ababsa - Floris Chevallier - M. Yonehara - Masanobu Uchiyama - Aïcha Derdour - Florence Mon



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